Top and tail the pineapple, remove the skin and the nobbly bits. Halve then quarter and remove the core, slice each quarter into 2 or 3 slices so you have long lengths of pineapple. Skewer length ways. Put aside. place the chocolate in pieces into a pan, add the Malibu if using and gently heat. When the chocolate has melted add the cream stirring all the time ( you can add any juice you may have left over from the pineapple) when the sauce is thick and smooth place a sheet of foil on the rack over the barbeque and douse the pineapple skewers with the sugar. Lay the skewers on the foil and barbeque until caramelised. Leave them to cool for a moment then dip into the chocolate sauce.
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